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Next: Geometric line cut Up: Simulation of STM images Previous: Introduction

Experiment

Carbon nanotubes were produced by catalytic decomposition of acetylene over a supported transition metal catalyst[3,4]. STM samples have been prepared[5] by ultrasonication of nanotube containing material purified from the catalyst.

In Fig. 1. the STM image and the corresponding line cut are shown for a carbon nanotube placed over other carbon nanotubes stacked in a regular way, i. e. on a ''raft''. Ratio of measured half width, HW, to measured height, h, is close to unity. This means that an apparent broadening, (defined as B = 2 HW / h), by a factor of 2.18 is present in the image.

Figure 1: STM measurement on a carbon nanotube placed on other nanotubes: a) constant current image of a ''raft'' of carbon nanotubes, $I_t = 0.19 \, nA$, $U_t = 302 \, mV$; b) line cut marked in the image is taken through a tube well separated from other tubes. HW/h ratio is close to unity.

In Fig. 2., we show an STM image acquired over a nanotube on HOPG. Apparent broadening from comparison of HW with h is B = 3.24. If one takes in account that the nanotube floats over the support at a height of $0.335 \, nm$,then the corrected broadening BC is: BC = 2.85 for nanotube over the raft, and BC = 4.29 for nanotube over HOPG.

Figure 2: STM measurement on a carbon nanotube placed on graphite: a) constant current image of individual nanotubes (A and C) and of a ''raft'' (B) composed of four nanotubes, $I_t = 0.22 \, nA$, $U_t = 410 \, mV$; b) line cut marked in the image is taken through object A. HW/h ratio is 3.24.



next up previous
Next: Geometric line cut Up: Simulation of STM images Previous: Introduction